个人简介
姚志远，男，副教授，硕士生导师，博士。
联系方式：zyyao@njtech.edu.cn；办公地点：笃行245。
主要从事钒基化合物结构设计与功能性质研究：
1.钒基水系锌离子电池正极材料结构设计与电化学性能研究;
2.新型钒氧酸盐离子导体制备和导电性质研究；
3.钒氧酸盐零/负热膨胀材料结构设计及热膨胀机理研究。
招生方向
物理学、材料科学与工程、化学工程与技术、应用化学
教学工作
讲授《薄膜技术》、《薄膜物理与技术》、《前沿科学讲座》等本科及研究生课程。
科研情况
迄今以第一作者或通讯作者身份在ACS Applied Materials & Interfaces、Journal of Materials Chemistry C、Inorganic Chemistry Frontiers、Physical Chemistry Chemical Physics、Dalton Transactions、CrystEngComm等国际学术期刊发表SCI论文13篇，并主持国家自然科学基金青年科学基金项目1项，参与面上项目2项。
1.科研项目：
（1）国家自然科学基金青年基金，层状钒氧酸盐新型零/负热膨胀材料结构设计与热膨胀机理研究，主持，2023.01–2025.12。
（2）国家自然科学基金面上基金，MOFs基锂/钠离子电池正极材料的结构设计、制备和离子导电性质研究，参与，2018.01–2021.12。
（3）国家自然科学基金面上基金，三维开骨架杂化固态质子导体多晶薄膜制备和导电性质, 参与，2017.01–2020.12。
2.代表性论文：
[1]Zhi-Yuan Yao, Yin Qian, Qiu Ren, Guo-Qin Zhang, Jin Zhang, Wen-Long Liu, Hong-Bin Luo, Xiao-Ming Ren*. Order-disorder transformation of intercalated cations triggering huge negative thermal expansion, switchable dielectrics and ion conduction near room temperature in a 2D vanadium oxide hybrid. J. Mater. Chem. C 2019, 7, 13243−13252.
[2]Zhi-Yuan Yao, Guo-Qin Zhang, Jian-Lan Liu, Jin Zhang, Wen-Long Liu, Xiao-Ming Ren*. CsCl-type inorganic cluster-based high-symmetry crystal built from {Mo4.55V7.45PO40}10.45- with high ratio of vanadium to molybdenum and {(H2O)0.3@K6(H2O)12}6+ clusters exhibiting proton conduction below the freezing point of water. Dalton Trans. 2019, 48, 17210−17216.
[3]Zhi-Yuan Yao, Guo-Qin Zhang, Wan-Wan Yao, Xiao-Zu Wang, Yin Qian, Xiao-Ming Ren*. Uniaxial thermal expansion behaviors and ionic conduction in a layered (NH4)2V3O8. Dalton Trans. 2020, 49, 10638−10644.
[4]Zhi-Yuan Yao, Guo-Qin Zhang, Zi-Han Li, Lin-Jiang Shen, Xiao-Ming Ren*. Structure-directing effect of aqueous alkali metal ion (Li+, Na+ and K+) clusters on the polyoxoanion configuration in vanadium-molybdenum polyoxometalate solid solutions, CrystEngComm 2021, 23, 6533−6540.
[5]Zhi-Yuan Yao*, Zi-Han Li, Xiao-Luan Xie, Yang Zou, Xiao-Ming Ren*. Reversible crystal−amorphous transformation assisted by loss and adsorption of coordination water molecules and ionic conduction in two isomorphous decavanadate-type polyoxometalates. J. Solid State Chem. 2022, 314, 123309.
[6]Zhi-Yuan Yao, Yang Zou, Xin Chen, Xiao-Ming Ren*. Crystal structure, hirshfeld surface, novel XPS spectroscopy and magnetic properties of a hybrid solid with tetrahedral coordination sphere tetrabromocuprate (II). Inorg. Chem. Commun. 2017, 81, 5−7.
[7]Zi-Han Li, Zhi-Yuan Yao*, Xiao-Luan Xie, Song Wang, Yan Zou, Hai-Jiao Yu, Xiao-Ming Ren*. Decavanadate-type polyoxometalate anions encapsulated in MIL-100 framework with enhanced mixed ion-electron conduction and potential application as cathode materials for lithium ion battery. ACS Appl. Eng. Mater. 2023, 1, 350−358.
[8]Xiao-Luan Xie, Song Wang, Da-Wei Gu, Zhi-Yuan Yao*, Yang Zou*, Xiao-Ming Ren, Mixed-dimensional (2D/3D/3D) heterostructured vanadium oxide with rich oxygen vacancies for aqueous zinc ion batteries with high capacity and long cycling life. ACS Appl. Mater. Interfaces 2024, 16, 8679−8687.
[9]Song Wang, Zhi-Yuan Yao*, Yi-Fan Li, Xiao-Luan Xie, Cheng Wang, Da-Wei Gu, Lei Wang, Yi-Hao Tang, Ze-Rui Xing, Yang Zou*, Xiao-Ming Ren, Temperature-dependent transformation of decavanadate-type {V10O28}6- clusters into {V3O7}- layer structures mediated by 3-quinuclidinol as a structural templating agent: Crystal architectures and mechanism. J. Solid State Chem. 2024, 337, 124811.
[10]Xiao-Luan Xie, Yi-Fan Li, Cheng Wang, Da-Wei Gu, Lei Wang, Qiao Qiao, Yang Zou, Zhi-Yuan Yao*, Lin-Jiang Shen, Xiao-Ming Ren. Expansion counteraction effect assisted vanadate with rich oxygen vacancies as a high cyclin stability cathode for aqueous zinc-ion batteries. Phys. Chem. Chem. Phys. 2025, 27, 3469−3476.
[11]Yi-Fan Li, Zhi-Yuan Yao*, Cheng Wang, Ke-Fan Wang, Da-Wei Gu, Lei Wang, Yang Zou, Xiao-Ming Ren. Multiple heterostructures, rich oxygen vacancies and expansion counteraction effect co-boosted VO2/V2O3/V6O13@nitrogen-doped carbon nanosheets as a high-performance cathode for aqueous zinc-ion batteries. Dalton Trans. 2025, 54,7004−7013.
[12]Ke-Fan Wang, Ding-Jie Ma, Zi-Qian Zeng, Cheng Wang, Yang Zou, Qiao Qiao, Zhi-Yuan Yao*, Xiao-Ming Ren. High-performance cathode for aqueous zinc-ion batteries: a novel lithium vanadate heterojunction with excellent mixed lithium-ion and electron conduction derived from decavanadate-type polyoxometalate. Inorg. Chem. Front. 2026, 13, 4559–4569.
[13]Cheng Wang, Zi-Qian Zeng, Ke-Fan Wang, Ding-Jie Ma, Yang Zou, Qiao Qiao, Zhi-Yuan Yao*, Xiao-Ming Ren*. Synergistic effect of electrolyte and intercalation engineering: comprehensive enhancement of the electrochemical performance of a mixed proton-electron conducting layered vanadate cathode for aqueous zinc-ion batteries. Dalton Trans. 2026, 55, 8508–8516.
当前位置